What behavior characterizes the oxides and halides of heavier Group 15 elements?

Prepare for the ACS Inorganic Chemistry Exam. Study using flashcards and multiple-choice questions, each with hints and explanations.

The correct answer is associated with the behavior of heavier Group 15 elements, such as phosphorus, arsenic, antimony, and bismuth, in relation to their oxides and halides. These elements can indeed act as Lewis acids due to the presence of accessible empty d orbitals. Heavier Group 15 elements can accept electron pairs, allowing them to participate in Lewis acid-base reactions.

As the atomic number increases, these elements exhibit a higher capacity for oxidation and can form stable compounds with electronegative species, further reinforcing their Lewis acid characteristics. For example, phosphorus trichloride (PCl3) can accept electron pairs from Lewis bases, making it act as a Lewis acid in chemical reactions.

The other options touch on various characteristics but do not accurately represent the typical behavior of these compounds. The notion that they do not form acids overlooks the formation of oxyacids, where the oxides of these heavier elements can lead to acid formation when reacting with water. While some of the compounds might show inert characteristics in specific scenarios, it does not holistically describe their behavior across the board. Similarly, while some oxides may act as Lewis bases, this is often less prevalent than their ability to act as Lewis acids, especially in

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