What condition describes a thermodynamically favorable reaction that is kinetically slow?

Prepare for the ACS Inorganic Chemistry Exam. Study using flashcards and multiple-choice questions, each with hints and explanations.

A thermodynamically favorable reaction is one that has a negative Gibbs free energy change (ΔG < 0), indicating that the products are more stable than the reactants under standard conditions. However, even if a reaction is thermodynamically favorable, it can still occur very slowly if certain conditions inhibit the rate of the reaction.

Choosing the condition where multiple electrons must move simultaneously helps illustrate why the reaction may be slow. In many redox reactions, when multiple electrons are involved, the complexity of electron transfer can create a significant energy barrier that needs to be overcome. This barrier is often associated with the rearrangement of bonds or the coordination of complexes, resulting in a slower reaction rate.

This contrasts with other options, such as the standard potential being less than zero or equal to zero, which do not directly indicate kinetic aspects or reaction rates, but rather the driving force for the reaction. Similarly, while high temperatures can increase the kinetic energy of the molecules involved, they do not inherently resolve issues related to electron transfer mechanisms that dictate whether the reaction is fast or slow.

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