What determines how much water can be polarized by a metal atom?

Prepare for the ACS Inorganic Chemistry Exam. Study using flashcards and multiple-choice questions, each with hints and explanations.

The ability of water to be polarized by a metal atom is closely related to the size of the metal atom. Larger metal atoms generally have a greater ability to polarize water molecules due to their lower charge density. In other words, as atomic size increases, the outer electrons are further from the nucleus and less tightly held, leading to a greater influence over nearby polar molecules like water. This allows the metal's positive charge to distort the electron cloud of the water molecule, enhancing the polarization effect.

While other factors such as the number of d-electrons, the reactivity of the metal, and the electronegativity of the metal may influence different chemical properties, they do not directly determine the degree to which water can be polarized by the metal atom. For instance, d-electrons can affect the bonding and coordination of metals within complexes, while the metal's reactivity relates more to its tendency to undergo chemical reactions. Electronegativity provides insight into the tendency of an atom to attract electrons but does not specifically address its capacity for polarizing surrounding molecules.

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