What does a high proton gain enthalpy indicate?

Prepare for the ACS Inorganic Chemistry Exam. Study using flashcards and multiple-choice questions, each with hints and explanations.

A high proton gain enthalpy indicates a strong basicity of the substance. This means that the substance has a strong tendency to attract protons (H⁺ ions) and thus can effectively function as a base. The concept of proton gain enthalpy refers to the energy change associated with the addition of a proton to a molecule or ion.

When a substance exhibits high proton gain enthalpy, it suggests that the process of protonation is energetically favorable, which typically corresponds to a strong basic character. Strong bases are able to stabilize the positive charge that results from gaining a proton, and they possess higher enthalpy values because they can release significant energy when they react with protons.

In contrast, other options may not accurately reflect the relationship between proton gain enthalpy and basicity. For instance, strong exothermic reactions do not necessarily relate to proton gain enthalpy specifically but rather indicate reactions that release energy broadly. The characterization of a very weak acid would imply a low tendency to donate protons rather than attract them. Finally, a negligible change in energy during proton transfer would suggest that the substance is neither strongly basic nor inherently favorable for protonation. Thus, indicating that a high proton gain enthalpy corresponds

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