What is the g value for a free electron?

Prepare for the ACS Inorganic Chemistry Exam. Study using flashcards and multiple-choice questions, each with hints and explanations.

The g value, or Landé g-factor, for a free electron is approximately 2.0023. This value arises from the interaction of the electron's spin and its magnetic moment in a magnetic field. The slight deviation from 2.0000 is due to quantum electrodynamics effects and the interactions of the electron with virtual particles in the vacuum, which slightly modifies its effective magnetic moment.

In the context of free electrons, the fundamental principles governing their behavior under magnetic influences suggest that they behave like point particles with a well-defined spin. The g value reflects how an electron's intrinsic properties behave in an external magnetic field, influencing magnetic resonance phenomena such as electron paramagnetic resonance (EPR) and magnetic resonance imaging (MRI).

The options that deviate significantly from 2.0023, such as the value of 1.0000 or 3.0000, do not correctly represent the physical reality of a free electron's magnetic behavior. The value of 1.9980 is very close to the correct one but does not account for all the factors leading to the more precise measurement of 2.0023. Thus, understanding the nuances of the g factor is key in the field of quantum mechanics and materials science,

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