What type of interaction is described as a van der Waals interaction?

Prepare for the ACS Inorganic Chemistry Exam. Study using flashcards and multiple-choice questions, each with hints and explanations.

Van der Waals interactions refer to the various types of attractive forces between molecules that do not result from covalent or ionic bonds, making option B the appropriate choice. These interactions arise from the fluctuations in electron distributions around atoms, leading to temporary dipoles that can induce dipoles in neighboring atoms or molecules. This concept encompasses several types of interactions, including dipole-dipole interactions, London dispersion forces, and dipole-induced dipole interactions.

Lattice enthalpy is influenced by the forces holding a solid's structure together, and van der Waals interactions contribute non-electrostatically to this balance. Because these interactions are weaker than ionic or covalent bonds and arise from simple physical phenomena of attraction, they fit into the broader category of non-electrostatic contributions.

Other options center on more specific or stronger interactions. Permanent dipole interactions are a type of dipole-dipole interaction and are just one particular mechanism within van der Waals forces. Electrostatic interactions typically refer to more significant forces between charged species, such as ions, which do not encompass the full spectrum of van der Waals interactions. Lastly, interactions specific to ionic compounds are particularly strong and stem from ionic bonds, which differ fundamentally from the weaker nature of van der Waals

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