What type of radiation is used in UPS?

Prepare for the ACS Inorganic Chemistry Exam. Study using flashcards and multiple-choice questions, each with hints and explanations.

The correct answer to the question regarding the type of radiation used in UPS (Ultraviolet Photoelectron Spectroscopy) is the helium discharge lamp. The helium discharge lamp emits ultraviolet light, specifically in the range of 21.2 eV to 40.8 eV, which is ideal for photoelectron spectroscopy applications.

UPS primarily utilizes ultraviolet radiation to excite electrons from the sample being analyzed. When helium is used in a discharge lamp, it provides a consistent and tunable source of UV light that can effectively ionize the sample, allowing for the measurement of photoelectron energies and intensities. This information is critical for determining the electronic structure and chemical composition of materials.

In contrast, other radiation types such as X-rays, lasers, or gamma radiation do not serve the same function in the context of UPS. X-ray sources are typically used in different types of spectroscopy, such as X-ray photoelectron spectroscopy, which focuses on different energy ranges and involves different mechanisms of ionization. Lasers can be employed in a variety of spectroscopic techniques but are not standard for UPS as they often operate at different wavelengths or energy levels not suited for describing valence electron states effectively. Gamma radiation is not utilized in spectroscopic methods focused on electronic transitions due to

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